(E)-1-(4-Hydroxybenzylidene)-4-methylthiosemicarbazide

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Synthesis and crystal structure of Schiff-base compound (E)-4-methoxy-N- (4-hydroxybenzylidene) aniline

New Schiff-base compound (E)-4-methoxy-N-(4-hydroxybenzylidene) aniline has been synthesized from the reaction of 4-hydroxybenzaldehyde with 4-methoxyaniline in methanol at 50ºC, and has been characterized by using elemental analysis and FT-IR spectroscopy. The crystal structure of the title compound has been determined by single crystal X-ray diffraction study. The title compound crystallizes ...

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(E)-4-[4-(Dimethyl­amino)styr­yl]-1-methyl­pyridinium 4-bromo­benzene­sulfonate1

In the title compound, C(16)H(19)N(2) (+)·C(6)H(4)BrO(3)S(-), the cation is nearly planar, with a dihedral angle of 3.19 (15)° between the pyridinium and the dimethylaminophenyl rings, and exists in the trans configuration. In the crystal packing, the cations and anions are linked into chains parallel to the c axis. These chains are stacked along the b axis. The crystal is stabilized by weak C-...

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(E)-1-(4-Bromo­phen­yl)-2-(4-tert-butyl­phen­yl)-1-phenyl­ethene

In the structure of the title compound, C(24)H(23)Br, the configuration about the double bond is E. The dihedral angles between the tert-butyl-substituted benzene ring and the unsubstituted and Br-substituted rings are 57.1 (2) and 78.2 (2)°, respectively. The methyl groups are disordered over two positions; the site occupancy factors are ca 0.8 and 0.2.

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4-Methyl­benzoic acid–N′-[(E)-4-methyl­benzyl­idene]pyridine-4-carbohydrazide–water (1/1/1)

In the title hydrated 1:1 adduct, C(8)H(8)O(2)·C(14)H(13)N(3)O·H(2)O, the Schiff base mol-ecule exists in an E conformation with respect to the N=C bond [1.2843 (13) Å] and the dihedral angle between the pyridine ring and the benzene ring is 1.04 (5)°. In the crystal, mol-ecules are linked by N-H⋯O, C-H⋯O, O-H⋯O and O-H⋯N hydrogen bonds into sheets lying parallel to the ab plane. The crystal st...

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ژورنال

عنوان ژورنال: IUCrData

سال: 2016

ISSN: 2414-3146

DOI: 10.1107/s2414314616010488